In this paper, the flame propagation characteristics and overpressure oscillation characteristics of CH4 explosion were studied under different ignition positions (IPs) and oxygen enrichment conditions in a half-open tube. The distances between the IP and the closed end of the tube are 0, 250, 500, and 750 mm. The oxygen enrichment coefficient (φ) values used in the experiment are 0.21, 0.3, and 0.4. The experimental results show that the IP and oxygen enrichment coefficient have an important influence on the flame structure and overpressure oscillation. Only when the oxygen enrichment coefficient φ = 0.21, a tulip flame will be formed. The IP close to the outlet can make the air participate in the combustion more quickly. With the increase of the oxygen enrichment coefficient, the combustion-induced rapid phase transition phenomenon is more likely to occur, and the maximum overpressure value and the overpressure rise rate of flame will increase. It is worth noting that after increasing the oxygen enrichment coefficient, the IP has less influence than the oxygen enrichment coefficient on the overpressure rise rate.Erythrodiol (3β-olean-12-ene-3, 28-diol) (C30H50O2) 1 is a nanosized oleanane-type fused 6-6-6-6-6 pentacyclic triterpeneoid extractable from the dried leaves of olive (Olea europia). One step reduction of oleanolic acid extracted from Lantana camara also yields the same compound. The triterpenoid has one secondary -OH group attached at C3 of the „A” ring and one primary -OH group at C28 present at the junction of the „D” and „E” rings. Here, we report the spontaneous self-assembly of erythrodiol in different neat organic liquids and aqueous-organic liquid mixtures. The nanosized dihydroxy triterpenoid having an oleanane-type lipophilic rigid skeleton self-assembled in liquids, yielding nanosized fibrils, microsized flowers, and grass-like architectures via formation of densely assembled fibrils and petals or 2D sheets. The microstructures of the self-assemblies have been characterized by different techniques like optical microscopy, electron microscopy, atomic force microscopy, FTIR, and wide angle X-ray diffraction studies. The porous self-assemblies having a large surface area obtained from 1 were capable of adsorbing toxic fluorophores like rhodamine-B, rhodamine-6G, methylene blue, and crystal violet (CV). Moreover, removal of the aforementioned toxic pigments has also been demonstrated from their aqueous solutions by using UV-visible spectrophotometry and epifluorescence microscopy.In the steam-assisted-gravity-drainage (SAGD) process, heat energy is transferred from the steam chamber to the farther cold reservoir by conduction and convection mechanisms, so as to reduce the oil viscosity. In previous research works, although it was proved that convection is an indispensable part of the heat-transfer process, there is still a controversy about the formation mechanism of heat convection. In this study, an analytical mathematic model was proposed to explore the convective heat transfer in SAGD operation. Typically, this model integrates three heat convection forms that are generated by pressure difference, gravity, and thermal expansion of connate water,. Subsequently, the simulation results are compared with field data to evaluate the accuracy of the new model, and they are reasonably consistent with UTF field data. The results indicate that convective heat transfer plays a predominant role in the immediate vicinity of the steam chamber interface. Furthermore, this paper derives a mathematic model of oil production to explore the effect of heat convection on oil production under different operation conditions. The results demonstrate that heat convection has an adverse impact on oil production, but it is inevitable. This study also displays that some parameters, such as the lateral spreading rate, the thermal diffusivity, the viscosity coefficient, and the curvature of oil relative permeability curve, can significantly affect the oil production rate. Based on this study, the effect of convection mechanism on the heat-transfer process and oil production will be further clarified, and the parameters in the SAGD process can be optimized, so as to effectively enhance and predict oil production.Large dielectric constants and small remanent polarization of the relaxor-ferroelectric (RFE) polymers are favored for energy-harvesting applications. Here, the energy harvesting of RFE thin films of vinylidene fluoride (VDF)-based terpolymers were re-evaluated. VDF-based terpolymers with trifluoroethylene (TrFE) and chlorofluoroethylene (CFE), CFE terpolymer, and those with TrFE and chlorotrifluoroethylene were used. Thermally annealed CFE terpolymer exhibited an energy density of 8.3 J cm-3 and an energy efficiency of 82% at a field of 280 MV m-1. The high-energy efficiency was related to the narrow bipolar hysteresis of displacement (D)-electric field (E) of the CFE terpolymer film. This narrow D-E hysteresis was a sum of the unipolar hysteresis directed toward the positive electric field region and that toward the negative electric field region, which suggested antiferroelectric-like behavior.Of several samples of polyvinyl pyrrolidone (PVP) used to coat and stabilize freshly manufactured aqueous dispersions of silver nanoparticles, one batch gave anomalous results the dispersion maintained continued stability, even on extensive dilution. Our efforts to understand this desirable feature concluded that the generally used spectral method of PVP purity verification, Fourier transform infrared (FTIR) spectroscopy, was incapable of answering our inquiry. This led to the employment of several other methods, including X-ray photoelectron and nuclear magnetic resonance spectroscopies, which ultimately revealed several possible reasons for the dilution stability, including incomplete PVP hydrolysis during manufacture and the presence of hydroperoxide contaminants. It led, as well, to explanations for the shortcomings of FTIR spectroscopy as a verification method for PVP purity.In this paper, we present the formation of reversible covalently cross-linked networks in ethylene propylene rubber with grafted anthracene groups (EPM-g-AN) based on the principles of photoinduced anthracene dimerization. First, an industrial-grade EPM rubber grafted with maleic anhydride functional groups (EPM-g-MA) was modified with 9-anthracenemethanol. By irradiating EPM-g-AN with UV light (365 nm), the anthracene moieties dimerize via [4 + 4]cycloaddition, forming a covalent network. The network cleavage proceeds at high temperatures (>170 °C), even if with considerable (chemical) degradation. Furthermore, one of the degradation routes has been identified by 1H NMR to occur via the ester bond cleavage releasing 9-anthracenemethanol. Nevertheless, the reversibility of cross-linking has been achieved by performing the reverse reaction in decalin. The UV-vis spectroscopy clearly shows that the de-cross-linking process in these conditions is due to the anthracene dimer cleavage. Although the recovery in mechanical properties upon recycling is yet to be optimized, the disclosed results pave the way toward the use of anthracene chemistry in thermally reversible networks with possible industrial perspective applications.In this work, well-dispersed fumed SiO2/cis-1,4-polyisoprene rubber (IR) masterbatch was first obtained through an effective wet mixing method, and the properties of the corresponding vulcanizate were studied. Before curing with activator and sulfur, IR solution was blended and co-coagulated with SiO2 suspension modified by bis(3-trimethoxysilypropyl) tetrasulfide in n-hexane. The modification of TESPT imparted evenly distributed SiO2 particles in IR and improved interfacial binding among SiO2 and IR. Hence, the prepared compound presented better processability and the corresponding vulcanizate presented higher physical performance, including higher tensile strength, lower heat buildup, and better fatigue resistance than that prepared in the dry mixing method. Additionally, higher wet skid resistance and lower rolling resistance could be observed in fabricated SiO2/IR vulcanizate. The employed wet mixing method is economical and efficient, which is promising in preparing rubber composites with comprehensive performance.Multiple myeloma (MM) is a hematological malignancy characterized by abnormal plasma cell proliferation within the bone marrow which leads to progressive bone marrow failure, skeletal osteolytic lesions, and renal insufficiency, thus severely affecting the quality of life. MM is always preceded by monoclonal gammopathy of uncertain significance (MGUS), which progresses to asymptomatic-MM (aMM) or symptomatic-MM (sMM) at a rate of 1% per year. Despite impressive progress in the therapy of the disease, MM remains incurable. Based on these premises, the identification of biomarkers of MGUS progression to MM is a crucial issue in disease management. In this regard, exosomes (EXs) and their precious biomolecular cargo could play a pivotal role in MM detection, stratification, and follow-up. Raman spectroscopy, a label- and manipulation-free technique, and its enhanced version, surface-enhanced Raman spectroscopy (SERS), have been used for characterizing MGUS, aMM, and sMM patient-derived EXs. Here, we have demonstrated the capability of Raman spectroscopy for discriminating EXs along the progression from MGUS to aMM and sMM, thus providing useful clinical indications for patient care. The used SERS devices, based on random nanostructures, have shown good potential in terms of sensitivity, but further developments are needed for achieving reproducible and quantitative SERS results.Repeatability is of utmost importance as it is directly linked to measurement accuracy and precision of a technique and affects its cost, utility, and commercialization. The present paper contributes to explain enhanced repeatability of the femtosecond laser-induced breakdown spectroscopy (fs-LIBS) technique, remarkably significant for its industrial applications and instrumental size reduction. A fs-laser with 7 mJ pulse energy was focused to create a transient titanium plasma, and a high-resolution spectrometer was used to study time-resolved spectra and single-shot drilling sampling repeatability. Time-resolved spectroscopy study at a delay time interval of 0-1600 ns showed 200-400 ns as the optimum delay time zone for data acquisition with 2-4% line intensity RSDs. Plasma temperature RSDs were less then 1.8% for the investigated delay interval and reached 0.5% at 200 ns where the temperature recorded a maximum value of 22,000 K. Electron density reached 5.7 × 1017 cm-3 at 200 ns, and RSDs were less then 3% with the least fluctuation of 0.7%. Shot-to-shot RSDs were 3.5-5% at 15-30 drilling shot intervals for line intensities, less then 2% for plasma temperature, and less then 6.5% for electron density. Using an uncertainty propagation formula, total number density RSDs were calculated to be 1.9-5.3% for 50 single-shot drilling scenarios. Considering physics behind results, fs-plasmas are „stable ablation sources” due to their electrostatic formation mechanisms and confined hydrodynamic evolution. The fs-laser opens up new directions for LIBS applications where accuracy is significantly enhanced.